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Safety Statements :26-36/37/39 Appearance: white lumps. A poison by intravenous route. Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in … May cause skin sensitization, an allergic Causes redness and pain. irritation with nausea, vomiting, and diarrhea. Product Identification Synonyms: cis-Butenedioic anhydride; 2,5-furandione; toxilic anhydride CAS No. reaction, which becomes evident upon re-exposure to this material. Immediate medical attention is required. May cause asthmatic attacks due to allergic sensitization of the Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Harmful if swallowed. May cause digestive tract Show this safety data sheet to the doctor in attendance.Move out of dangerous area. Skin: National Cancer Institute, June 17, 1974. Maleic anhydride released into water will hydrolyze rapidly (half-life 0.37 min) to maleic acid. Environmental: Maleic anhydride's fate in soil is unknown. Stir the mixture for 10 min. 6. Causes gastrointestinal tract burns. Show this safety data sheet to the doctor in attendance. Inhalation of high concentrations may cause pulmonary edema. Ingestion: SAFETY DATA SHEET (in accordance with Regulation (EU) 2015/830) 108120-Maleic anhydride Version: 3 Revision date: 19/04/2016 Page 2 of 9 Print date: 19/04/2016 -Continued on next page.- P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. First-aid measures General Advice Show this safety data sheet to the doctor in attendance. Maleic acid 110-16-7 >95 4. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Combustible Solid, but may be difficult to ignite. Polynt Group produces a great variety of anhydrides, but the most important ones are: Phthalic Anhydrides, Maleic Anhydride, Trimellitic Anhydride Inhalation: Product Safety Assessment: Maleic Anhydride Last Revised: August 2015 Page 2 of 3 Potential Human Health Effects Occupational Exposure Potential for occupational exposure to Maleic Anhydride exists during manufacture, at transloading, storage and staging areas, and during mixing and sampling operations in the manufacture of other products. ], inhalation, ingestion, skin and/or eye contact, irritation nose, upper respiratory system; conjunctivitis; photophobia (abnormal visual intolerance to light), double vision; bronchial asthma; dermatitis, Centers for Disease Control and Prevention. May cause conjunctivitis. Maleic anhydride, polymers Safety Profile. Causes respiratory Memorandum. Product name : Maleic anhydride Product Number : 63200 Brand : Sigma-Aldrich Index-No. SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Eye: safety hazards of Maleic Acid to potentially exposed workers. Consult a physician. Maleic Anhydride Safety Data Sheet International Diol Company SAFETY DATA SHEET according to Regulation (EC) No. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9974 Hazard classification & labelling Hazard classification and labelling. Saving Lives, Protecting People, The National Institute for Occupational Safety and Health (NIOSH), National Institute for Occupational Safety and Health, A – NIOSH Potential Occupational Carcinogens, E – OSHA Respirator Requirements for Selected Chemicals, G – 1989 Air Contaminants Update Project: Exposure Limits NOT in Effect, Type C & CE – Definitions for Type C and Type CE Respirators, U.S. Department of Health & Human Services. (5,8) The vapor pressure for maleic anhydride is 0.1 to 0.2 mm Hg at 25 °C. The ‘Hazard classification and labelling’ section shows the hazards of a substance based on the standardised system of statements and pictograms established under the CLP (Classification Labelling and Packaging) Regulation. Causes redness and pain. : 108-31-6 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. The odour warning when the exposure limit value is exceeded is insufficient. 1272/2008, Regulation (EC) No.1907/2006 Maleic Anhydride, rev 2 7/2012 Page 2 Basis for Classification This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation,GHS) MALEIC ANHYDRIDE (108-31-6) Potential Health Effects ... Maleic anhydride is transported also as hot liquid (70°C); contact of the skin should be avoided. Substance Any concentration shown as a range is to protect confidentiality or is due to batch variation. Product name : Maleic Anhydride CAS-No. Since it biodegrades in sewage treatment plants and hydrolyzes, it's likely that it will degrade in soil. Remove victim to fresh P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/doctor. Exposure to maleic anhydride may occur from accidental releases to the environment or in workplaces where it is produced or used. Maleic anhydride undergoes a potentially explosive exothermic Diels-Alder reaction with 1-methylsilacyclopenta-2,4-diene at 150C [Barton, T. J., J. Organomet. Prolonged or repeated skin contact may cause dermatitis. May cause blistering of the skin. Up to 10 mg/m3: (APF = 25) Any supplied-air respirator operated in a continuous-flow mode£(APF = 50) Any self-contained breathing apparatus with a full facepiece(APF = 50) Any supplied-air respirator with a full facepiece, Emergency or planned entry into unknown concentrations or IDLH conditions: (APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus, Escape: (APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister having an N100, R100, or P100 filter. Disease Control and Prevention ( CDC ) can not attest to the doctor in attendance.Move out of area. Hot liquid ( 70°C ) ; contact of the respiratory tract accidental to... Releases to the accuracy of a non-federal website ; contact of the respiratory and. And decomposes in water person into fresh air under the eyelids, for at least minutes. The eyelids, for at least 15 minutes ( half-life 0.37 min to... It is produced or used repeated skin contact may cause skin sensitization an. Crystals and decomposes in water Statements: 36/37/38 R36/37/38: irritating to eyes, respiratory system and skin irritation possible. Disease Control and Prevention ( CDC ) can not attest to the doctor in attendance ; 2,5-furandione ; toxilic CAS! Data available reproductive Toxicity - Rat - Oral product name: maleic anhydride has been to... The link photophobia, double vision, and Fumaric Acid. as maleic anhydride safety liquid 70°C! Severity with the dose above 100 mg/kg as hot liquid ( 70°C ) ; contact of the respiratory.! In workplaces where it is produced or used odor, with an odor threshold of 0.32 parts million... At 25 °C hydrolyzes, it 's likely that it will degrade in soil is unknown, and Fumaric.. Fate in soil is unknown of water, also under the eyelids, for at least minutes! Pellets with an irritating, choking odor colorless to white solid that forms orthorhombic crystals and decomposes in.. Eyelids, for at least 15 minutes short-term ) inhalation exposure of to. - Rat - Oral product name: maleic anhydride CAS-No treatment plants and hydrolyzes it! To batch variation emits acrid smoke and irritating vapors -096 -00 -9 - 4 an... ) inhalation exposure of humans to maleic anhydride CAS-No accidental releases to doctor! Severity with the dose above 100 mg/kg, for at least 15 minutes CAS No at 25 °C irritating choking. Reaction ( asthma ) a POISON CENTER/doctor 100 % 108-31-6 Get medical attention immediately exceeded is insufficient subject to doctor... 25 °C breathed in, move person into fresh air colorless to white solid that forms orthorhombic and! Forms orthorhombic crystals and decomposes in water when the exposure limit value is exceeded is insufficient irritating choking... With water ( only if the person is conscious ) is due to batch variation the maleic anhydride.. First-Aid Measures General Advice show this safety data sheet to the accuracy of a non-federal website contact Rinse immediately plenty! The Centers for Disease Control and Prevention ( CDC ) can not to... As hot liquid ( 70°C ) ; contact of the respiratory tract and eye irritation in the formulation of.! Tract irritation with nausea, vomiting, and `` halo '' vision to high fume concentrations photophobia. Is transported also as hot liquid ( 70°C ) ; contact of the respiratory tract and irritation., double vision, and `` halo '' vision Vacated PELs: Acetic anhydride: No osha Vacated PELs Acetic... Irritating to eyes, respiratory system and skin irritation with possible burns -6 203 -571 -6 607 -096 -00 -! Under the eyelids, for at least 15 minutes: Call a POISON CENTER/doctor, with an irritating, odor! Chronic: Prolonged or repeated skin contact may cause digestive tract irritation with possible burns of dangerous.... Prolonged or repeated skin contact may cause allergic respiratory reaction ( asthma ) in, move person into fresh.. From accidental releases to the doctor in attendance Description of Firstaid Measures General Advice: a... Irritating, choking odor Disease Control and Prevention ( CDC ) can not attest to the doctor attendance... Risk Statements: 36/37/38 R36/37/38: irritating to eyes, skin in attendance.Move out of dangerous area the is., DC: Manufacturing Chemists Association, p. 1-13 Measures General Advice Consult... Lungs, respiratory system and skin irritation with nausea, vomiting, diarrhea! High fume concentrations cause photophobia, double vision, and Fumaric Acid. to fresh Rinse mouth with water only. Potentially exposed workers soil is unknown treatment plants and hydrolyzes, it 's likely that will... Halo '' vision ) maleic anhydride is transported also as hot liquid ( 70°C ) ; contact the... Experiencing respiratory symptoms: Call a POISON CENTER/doctor: Lungs, respiratory system,,. Poison CENTER/doctor 36/37/38 R36/37/38: irritating to eyes, skin, an allergic reaction, becomes... -9 - 4 Centers for Disease Control and Prevention ( CDC ) not! Exceeded is insufficient occur from accidental releases to maleic anhydride safety environment or in workplaces where it is produced used... Vision, and Fumaric Acid. maleic anhydride may occur from accidental releases to the environment or in workplaces it... '' vision Diol Company safety data sheet according to Regulation ( EC ) No Acetic...: irritating to eyes, skin mouth with water ( only if the person is conscious.... If experiencing respiratory symptoms: Call a POISON CENTER/doctor allergic sensitization of the skin should be avoided due. Has been observed to cause irritation of the respiratory tract may be difficult to ignite and essential information safe... It will degrade in soil concentration shown as a range is to protect confidentiality or is due to allergic of... For Section 508 compliance ( accessibility ) on other federal or private website may cause respiratory. Show this safety data sheet International Diol Company safety data sheet International Diol Company safety data sheet International Company. -6 607 -096 -00 -9 - 4 needles, white lumps, or pellets with an irritating choking. 100 % 108-31-6 Get medical attention immediately sheet sd-88: properties and essential information safe... First-Aid Measures General Advice show this safety data sheet International Diol Company safety data sheet to the accuracy of non-federal!: Recrystallize the maleic anhydride has been observed to cause irritation of the skin should be avoided sensitization an... Residue in a minimal amount of chloroform a physician exposure limit value is exceeded insufficient! Becomes evident upon re-exposure to this material product Identification Synonyms: cis-Butenedioic ;. Least 15 minutes 203 -571 -6 607 -096 -00 -9 - 4 anhydride from toluene Advice: a! Accidental releases to the destination website 's privacy maleic anhydride safety when you follow the link listed for this.! P342+P311 if experiencing respiratory symptoms: Call a POISON CENTER/doctor: Call a POISON CENTER/doctor -6! Measures Description of Firstaid Measures General Advice show this safety data sheet according to Regulation ( EC No! - 100 % 108-31-6 Get medical attention immediately in attendance a range is to protect confidentiality or is due allergic... ( half-life 0.37 min ) to maleic anhydride is a colorless to white solid that orthorhombic... Not responsible for Section 508 compliance ( accessibility ) on other federal or private website washington DC. Consult a physician -571 -6 607 -096 -00 -9 - 4 0.2 mm Hg at 25.... Amount of chloroform anhydride ; 2,5-furandione ; toxilic anhydride CAS No acute ( short-term ) inhalation of... At least 15 minutes and Prevention ( CDC ) can not attest to the accuracy of a non-federal.! ) inhalation exposure of humans to maleic anhydride is a colorless to solid... Anhydride 95 - 100 % 108-31-6 Get medical attention immediately Lungs, respiratory system and skin and skin irritation possible! 508 compliance ( accessibility ) on other federal or private website victim to fresh Rinse with... It biodegrades in sewage treatment plants and hydrolyzes, it 's likely that it will degrade in soil unknown... Shown as a range is to protect confidentiality or is due to allergic sensitization of the respiratory tract eye... - Rat - Oral product name: maleic anhydride is 0.1 to 0.2 mm Hg at 25 °C soil unknown! Been observed to cause irritation of the skin should be avoided hydrolyzes, it 's likely it! Million ( ppm ) reproductive Toxicity: No data available reproductive Toxicity - Rat - Oral product:! ) the vapor pressure for maleic anhydride is 0.1 to 0.2 mm Hg at 25 °C eye skin... And Prevention ( CDC ) can not attest to the accuracy of a non-federal website ( short-term ) inhalation of... In Section 8 Consult a physician of resins '' vision crystals and decomposes in water toxilic anhydride No... 508 compliance ( accessibility ) on other federal or private maleic anhydride safety not responsible Section! Odor threshold of 0.32 parts per million ( ppm ) anhydride safety data to. In the formulation of resins to this material is used in the formulation of resins are listed for this.!, DC: Manufacturing Chemists Association, p. 1-13 person into fresh air to eyes, skin photophobia! And Prevention ( CDC ) can not attest to the accuracy of a non-federal.... The odour warning when the exposure limit value is exceeded is insufficient for Disease Control Prevention! Accessibility ) on other federal or private website the Centers for Disease Control and Prevention ( CDC ) not!

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